张小超
博士硕士生导师
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学 科:
化工
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研究方向:
高效新型太阳能光/电催化材料的可控制备及废油脂清洁利用、CO2绿色转化、水制氢、第一性原理计算等
- 邮箱:zhangxiaochao@tyut.edu.cn
- 地址:569vip威尼斯游戏迎西校区化工馆112
1.教育经历
2004年09月 安阳工学院化学工程与工艺专业 工学学士
2008年09月 569vip威尼斯游戏化学工程与技术专业 博士(导师:樊彩梅教授)
2.工作经历
2013年07月 569vip威尼斯游戏化学569vip威尼斯游戏 讲师
2017年12月 569vip威尼斯游戏 副教授
2023年01月 阳泉市能源局副局长(挂职学习)
3.学术奖励
2022年获山西省科学技术奖自然科学奖二等奖(张小超;王雅文;王韵芳;樊彩梅);
2022年获山西省科学技术奖自然科学奖三等奖(刘建新;李瑞;王韵芳;张小超;王雅文;樊彩梅);
2018年获第十九届山西省优秀学术论文一等奖 (高晓亚; 张小超(通讯作者); 王雅文; 彭仕琪; 岳斌; 樊彩梅);
2018年山西省“三晋英才”支持计划青年优秀人才;
2016年获第十八届中国科协年会全国科技工作者创新创业大赛银奖 (张继龙; 李瑞丰; 张小超; 易群; 王飞);
2018、2019、2020、2021年分别荣获全国化工设计大赛国家级二等奖、一等奖、特等奖、二等奖等。
开设课程
本科生课程:《化工计算与过程模拟》、《煤化工工艺学》
硕士研究生课程:《光电催化反应工程》、《计算物理化学》
一、基金项目
1. 国家面上自然基金项目,Z型功能化Bi基复合薄膜的原位构筑及高效光驱动CO2加氢脱氧机理研究,主持,2020-2023
2. 山西省优秀青年基金项目,Z型功能化BiOBr基复合薄膜的原位构筑及光催化还原CO2作用机制研究,主持,2018-2021
3. 山西省高等学校科技创新项目,2014115,单原子Pt/BiOX可见光还原CO2制甲烷的研究,主持,2018-2020
4. 国家青年自然基金项目,21506144,利用Pt/BiOX太阳能光催化废油脂脱羧及其反应特性研究,主持,2015-2018
5. 山西省青年自然基金项目,2014021019-3,贵金属修饰BiOBr薄膜的可控制备、光催化性能及反应机理研究,主持,2014-2017
6. 山西省高等学校科技创新项目,2014115,Ag/BiOBr薄膜的可控制备及光催化反应机理,主持,2014-2017
7. 569vip威尼斯游戏校人才引进启动资金,rc201348a,贵金属修饰BiOBr薄膜的可控制备、光催化性能及反应机理研究,主持,2014-2017
8. 569vip威尼斯游戏校青年基金,2013T086,高效太阳能光催化废油脂的脱羧反应途径及机理研究,主持,2014-2017
9. 山西省研究生创新项目,20113040,纳米卤氧铋太阳光光催化降解有机污染物的基础研究,主持,2011-2012
10. 太原市科技局人才专项,201010639,复合卤氧铋(BiOX)光催化剂的可控制备及性能研究,主持,2011-2012
二、代表性论文
1. Zhengfeng Shen; Feifei Li; Lijun Guo; Xiaochao Zhang; Yawen Wang; Yunfang Wang; Xuan Jian; Xiaoming Gao; Zhongde Wang; Rui Li; Caimei Fan; Jianxin Liu. Ligand bridged MXene/metal organic frameworks heterojunction for efficient photocatalytic ammonia synthesis[J]. Applied Catalysis B: Environment and Energy, 2024, 346: 123732.
2. Yuan Wang; Guomin Xu; Chao Xue; Changming Zhang; Jinbo Xue; Xiaochao Zhang*. Self-nitrogen-doped hierarchical porous carbon spheres as metal-free catalyst for efficient photocatalytic CO2 reduction[J]. Separation and Purification Technology, 2024: 127008.
3. Xiushuai Guan; Shanbiao Jin; Le Liu; Xiya Zhao; Xiaochao Zhang*; Changming Zhang; Zhong Li; Caimei Fan Surface engineering of CexBi1 xO2 δ nanorods rich in oxygen vacancies for enhancing photo-thermal synthesis of dimethyl carbonate from CO2/CH3OH[J]. Fuel, 2024, 358: 130215.
4. Changming Zhang; Yuan Wang; Xiaochao Zhang; Zhiyan Dong; Wensheng Wu; Caimei Fan. Self-nitrogen-doped carbon spheres assisted CeO2 composites as a bifunctional adsorbent/photocatalyst for CO2 photoreduction[J]. Fuel, 2024, 362: 130848.
5. Qing Xi; Fangxia Xie; Zijun Sun; Jianxin Liu; Xiaochao Zhang; Yawen Wang; Aijuan Zhou; Xiaoli Ma; Xiaoming Gao; Xiuping Yue; Jun Ren; Caimei Fan; Xuan Jian; Rui Li. NiRu–Mo 2 Ti 2 C 3 O 2 as an efficient catalyst for alkaline hydrogen evolution reactions: the role of bimetallic site interactions in promoting Volmer-step kinetics[J]. Physical Chemistry Chemical Physics, 2024, 26(8): 7166-7176.
6.. Jiangyong Yu; Shengqin Guan; Xiaochao Zhang; Baoen Xu; Taotao Guan; Kaixi Li; Jianlong Wang. Deep eutectic solvents based on cyclodextrin-monoethanolamine for high-efficiency carbon dioxide capture under high temperature[J]. Journal of Environmental Chemical Engineering, 2024, 12(1): 111625.
7. Xiushuai Guan; Shanbiao Jin; Le Liu; Xiya Zhao; Xiaochao Zhang*; Changming Zhan; Zhong Li; Caimei Fan. Surface engineering of CexBi1xO2δ nanorods rich in oxygen vacancies for enhancing photo-thermal synthesis of dimethyl carbonate from CO2/CH3OH[J]. Fuel, 2024, 358: 130215.
8. Shanbiao Jin; Xiushuai Guan; Xiaochao Zhang*; Changming Zhang; Jianxin Liu; Yawen Wang; Yunfang Wang; Rui Li; Zhong Li; Caimei Fan. CeO2 nanorods with bifunctional oxygen vacancies for promoting low-pressure photothermocatalytic CO2 conversion with CH3OH to dimethyl carbonate[J]. Journal of Environmental Chemical Engineering, 2023, 11(6): 111374.
9. Qing Xi; Fangxia Xie; Jianxin Liu; Xiaochao Zhang; Jiancheng Wang; Yawen Wang; Yunfang Wang; Houfen Li; Zhuobin Yu; Zijun Sun; Xuan Jian; Xiaoming Gao; Jun Ren; Caimei Fan; Rui Li. In Situ Formation ZnIn2S4/Mo2TiC2 Schottky Junction for Accelerating Photocatalytic Hydrogen Evolution Kinetics: Manipulation of Local Coordination and Electronic Structure[J]. Small, 2023: 2300717.
10. Guangmin Ren; Zixuan Wei; Zizhen Li; Xiaochao Zhang*; Xiangchao Meng. Fabrication of S-scheme hollow TiO2@ Bi2MoO6 composite for efficiently photocatalytic CO2 reduction[J]. Materials Today Chemistry, 2023, 27: 101260.
11. Lulu Zhang; Rui Li; Luyao Cui; Zijun Sun; Lijun Guo; Xiaochao Zhang; Yunfang Wang; Yawen Wang; Zhuobin Yu; Tao Lei; Xuan Jian; Xiaoming Gao; Caimei Fan; Jianxin Liu. Boosting photocatalytic ammonia synthesis performance over OVs-Rich Ru/W18O49: Insights into the roles of oxygen vacancies in enhanced hydrogen spillover effect[J]. Chemical Engineering Journal, 2023, 461: 141892.
12. Xiushuai Guan; Xiaochao Zhang* ; Changming Zhang; Rui Li; Jianxin Liu; Yunfang Wang; Yawen Wang; Caimei Fan; Zhong Li. Original self-assembled S-scheme BiOBr-(0 0 1)/Bi2SiO5/Bi heterojunction photocatalyst with rich oxygen vacancy for boosting CO2 reduction performance[J]. Journal of Colloid and Interface Science, 2023, 644: 426-436.
13. Yuzhao Wang; Fangxia Xie; Rui Li; Zhuobin Yu; Xuan Jian; Xiaoming Gao; Houfen Li; Xiao Zhang; Jianxin Liu; Xiaochao Zhang; Yawen Wang; Caimei Fan; Xiuping Yue; Aijuan Zhou. Bi3O4Br/Ti3C2 Schottky junction with enhanced active species generation for boosting visible-light photodegradation bisphenol A activity[J]. Separation and Purification Technology, 2023, 318: 124001.
14. Jiali Wang; Zijun Sun; Yaru Li; Lijun Guo; Yunfang Wang; Caimei Fan; Yawen Wang; Rui Li; Xiaochao Zhang; Feifei Li; Zhuobin Yu; Jianxin Liu. Sulfur vacancy MoS2 for electrocatalytic reduction of nitrate to ammonia with enhanced selectivity[J]. Journal of Alloys and Compounds, 2023, 955: 170199.
15. Qiaoxia Zhu; Fangxia Xie; Jianxin Liu; Xuan Jian; Zhuobin Yu; Xiaoming Gao; Houfen Li; Xiaochao Zhang; Yawen Wang; Yunfang Wang; Caimei Fan; Rui Li. Anchoring Ru Nanoparticles on Ti3C2Tx for Accelerated Alkaline Hydrogen Evolution Reaction: the Effect of Electronic Metal-Support Interaction[J]. Journal of Alloys and Compounds, 2023: 170764.
16. Lulu Zhang; Fangxia Xie; Jianxin Liu; Zijun Sun; Xiaochao Zhang; Yawen Wang; Yunfang Wang; Rui Li; Caimei Fan. Light-switchable oxygen vacancies enhanced nitrogen fixation performance on BiOBr: mechanism of formation, Reconversion and Function[J]. Chemical Engineering Journal, 2022, 450: 138066.
17. Xiushuai Guan; Xiaochao Zhang*; Changming Zhang; Rui Li; Jianxin Liu; Yunfang Wang; Yawen Wang; Caimei Fan; Zhong Li. In Situ Hydrothermal Synthesis of Metallic Bi Self‐Deposited Bi2SiO5 with Enhanced Photocatalytic CO2 Reduction Performance[J]. Solar RRL, 2022, 6(9): 2200346.
18. Fangxia Xie; Qing Xi; Houfen Li; Xuan Jian; Jianxin Liu; Xiaochao Zhang; Yawen Wang; Rui Li; Caimei Fan. Two-dimensional/two-dimensional heterojunction-induced accelerated charge transfer for photocatalytic hydrogen evolution over Bi5O7Br/Ti3C2: Electronic directional transport[J]. Journal of Colloid and Interface Science, 2022, 617: 53-64.
19. Zhifei Wanga; Jinbo Xue; Yong Li; Qianqian Shen; Qi Li; Xiaochao Zhang; Xuguang Liua; Husheng Jia. Robust Fe2+-doped nickel-iron layered double hydroxide electrode for electrocatalytic reduction of hexavalent chromium by pulsed potential method[J]. Journal of Materials Science & Technology, 2022, 110: 73-83.
20. Yaru Li; Jianxin Liu; Zijun Sun; Rui Li; Lijun Guo; Xiaochao Zhang; Yawen Wang; Yunfang Wang; Zhuobin Yu and Caimei Fan. Enhanced photocatalytic ammonia synthesis over a Bi/carbon cloth float: triphase reaction system-assisted N2 supply and photothermal co-activation[J]. Green Chemistry, 2022, 24(23): 9253-9262.
21. Zijun Sun;ab Rui Li; Qing Xi; Fangxia Xie; Xuan Jian; Xiaoming Gao; Houfen Li; Zhuobin Yu; Jianxin Liu; Xiaochao Zhang; Yawen Wang; Yunfang Wang; Xiuping Yue; Caimei Fan. Single atom supported on MXenes for the alkaline hydrogen evolution reaction: species, coordination environment, and action mechanism[J]. Physical Chemistry Chemical Physics, 2023, 25(19): 13728-13740.
22. Xiaochao Zhang*; Tan Li; Xiushuai Guan; Changming Zhang; Rui Li; Jinbo Xue; Jianxin Liu; Yawen Wang; Caimei Fan. Theoretical insights into effective electron transfer and migration behavior for CO2 reduction on the BiOBr(001) surfaces[J]. Physical Chemistry Chemical Physics, 2022, 24(4): 2032-2039.
23. Rongxian Wang; Lifang Kou; Changming Zhang; Xiaochao Zhang*; Yunfang Wang; Caimei Fan. Single-step synthesis of novel Bi2Fe4O9 nanosheets for high-efficient photocatalytic CO2 reduction to CO[J]. Materials Letters, 2022, 314: 131932.
24. Fangxia Xie; Qing Xi; Houfen Li; Xuan Jian; Jianxin Liu; Xiaochao Zhang; Yawen Wang; Rui Li; Caimei Fan. Two-dimensional/two-dimensional heterojunction-induced accelerated charge transfer for photocatalytic hydrogen evolution over Bi5O7Br/Ti3C2: electronic directional transport[J]. Journal of Colloid and Interface Science, 2022, 617: 53-64.
25. Jiaqi Gao; Jinbo Xue; Qianqian Shen; Tianwu Liu; Xiaochao Zhang; Xuguang Liu; Husheng Jia; Qi Li; Yucheng Wu. A promoted photocatalysis system trade-off between thermodynamic and kinetic via hierarchical distribution dual-defects for efficient H2 evolution[J]. Chemical Engineering Journal, 2022, 431: 133281.
26. Meihua Guan; Guangmin Ren; Xiaochao Zhang*; Qirui Zhang; Changming Zhang; Rui Li; Caimei Fan. Regulating electronic properties of BiOBr to enhance visible light response via 3d transition metals doping: DFT+U calculations[J]. International Journal of Quantum Chemistry, 2020, 121(7): e26568.
27. Changming Zhang; Yaqi Wang; Xiaochao Zhang*; Rongxian Wang; Lifang Kou; Jiancheng Wang; Rui Li; Caimei Fan. Millimeter-level nitrogen modified activated carbon spheres assisted Bi4Ti3O12 composites for bifunctional adsorption/photoreduction of CO2[J]. Chemical Engineering Journal, 2021, 417: 128218.
28. Changming Zhang; Rongxian Wang; Yaqi Wang; Guangmin Ren; Xiaochao Zhang; Rui Li; Caimei Fan. Synthesis of millimeter-sized porous carbon spheres derived from different precursors for CO2 capture[J]. Journal of Porous Materials, 2021, 28(1): 81-91.
29. 张小超*; 管美画; 张启瑞; 张长明; 李瑞; 刘建新; 王雅文; 樊彩梅. 单原子Pt吸附于不同原子暴露终端BiOBr{001}面的第一性原理研究[J]. 物理学报, 2021, 70(8): 345-354.
30. Xiaochao Zhang*; Tan Li; Meihua Guan; Rui Li; Jianxin Liu; Yawen Wang; Changming Zhang; Caimei Fan. DFT insights into the migration of effective electrons towards O2 for center dot OH formation over electron-rich 31. Changming Zhang*; Xiaoxia Ren; Lifang Kou; Xiaochao Zhang; Rongxian Wang; Lijing Xie; Caimei Fan. Facile synthesis of nitrogen-rich porous carbon spheres assisted by NaNH2 as a bifunctional activator and nitrogen source for CO2 capture[J]. Journal of Environmental Chemical Engineering, 2021, 9: 106605.
32. Xiaochao Zhang*; Guangmin Ren; Changming Zhang; Jinbo Xue; Qiang Zhao; Rui Li; Yunfang Wang; Caimei Fan. Assisting Bi2MoO6 microspheres with phenolic resin-based ACSs as attractive tailor-made supporter for highly-efficient photocatalytic CO2 reduction[J]. Green Energy & Environment, 2021, 6(5): 693-702.
33. Xiaochao Zhang*; Tingting Xue; Changming Zhang; Jiancheng Wang; Jinbo Xue; Rui Li; Yawen Wang; Caimei Fan. In situ synthesis of hydrangea finch coral-like Bi12SiO20 film with highly effective photocatalytic CO2 reduction performance[J]. ACS Applied Energy Materials, 2021, 4(1): 15-19.
三、授权专利
1. 张小超; 官修帅; 任广敏; 张长明; 李瑞; 王韵芳; 樊彩梅, 一种Bi/Bi2SiO5光催化剂的制备方法及其应用, 中国,ZL 201910891546.3
2. 张小超; 薛婷婷; 任广敏; 张长明; 李瑞; 王韵芳; 樊彩梅, 一种BiOBr/Bi12SiO20复合薄膜光催化剂的电化学制备方法及其应用, 中国,ZL 201910891326.0
3. 张长明; 张小超; 杨艳青; 宋雯; 高颖; 李瑞, 一种钒铜改性脱汞吸附材料及其制备方法及其应用, 中国,ZL 201711229198.0
4. 张小超; 李瑜; 李双志; 李瑞; 赵祖; 张长明; 王韵芳; 王雅文; 刘建新; 樊彩梅, 一种纳米片状氟化铋薄膜的电化学制备方法及其应用, 中国, ZL 201711021123.3
5. 李瑞; 张小超; 李双志; 赵祖; 张长明; 刘建新; 王韵芳; 王雅文; 樊彩梅, 一种钨酸铋光催化薄膜的电化学制备方法及其应用, 中国, ZL 201711021098.9
6. 樊彩梅; 吕瑞; 胡颖媛; 贾泽慧; 刘建新; 张小超; 李瑞; 王雅文; 王韵芳, 一种降解水中苯酚的复合光催化剂薄膜的制备方法, 中国, ZL 201711012186.2
7. 樊彩梅; 李瑞; 李双志; 谢芳霞; 王雅文; 张小超; 王韵芳, 一种Bi12O17Br2光催化剂的合成及应用方法, 中国, ZL 201611068638.4
8. 樊彩梅; 胡颖媛; 李双志; 张小超; 王雅文; 王韵芳; 丁光月, 一种复合薄膜光催化剂BiPO4/BiOCl的电化学制备及应用方法, 中国, ZL 201610176702.4
9. 张长明; 张小超; 宋雯; 张继龙; 易群; 鲁冰倩; 李瑞, 一种BiOBr/NiO@ACSs球形复合光催化剂的制备方法, 中国, ZL 201510638283.7
10. 张长明; 张小超; 宋雯; 高颖; 李瑞, 一种Co3O4@ACSs/BiOCl球形吸附-光催化复合催化剂的制备方法, 中国, ZL 201510675366.3
11. 王韵芳; 王雅文; 张雪; 樊彩梅; 丁光月; 张小超, 一种AgBr/CuO可见光光催化材料的再生方法及其应用, 中国, ZL 201410457258.4
12. 张小超; 李瑞; 张继龙; 易群; 樊彩梅, 一种水相分散型光催化剂及其制备方法和应用, 中国, ZL 201410477422.8
13. 张小超; 李瑞; 张继龙; 易群; 鲁冰倩, 一种微乳状光催化剂及其制备方法和应用, 中国, ZL 201410477445.9
14. 张继龙; 张小超; 易群; 杜朕屹; 郑华艳; 荆洁颖; 陈广建; 郑静, 一种生物柴油的生产装置及生产方法, 中国, ZL 201410261146.1
15. 张小超; 易群; 张继龙; 郭天玉; 李国旗, 一种用动植物油脂及废弃油制备煤浮选剂的方法, 中国, ZL 20116. 易群; 张小超; 张继龙; 郭天玉; 任晓霞, 一种焦化行业废弃油综合利用的方法, 中国, ZL 201310464470.9